MCQChemistry

NCERT · Class 12 · Chemistry · Coordination CompoundsAccording to Crystal Field Theory (CFT), what causes the splitting of d-orbitals in octahedral complexes?

Step-by-Step Solution

Crystal Field Theory treats ligands as point charges that create an electrostatic field. In an octahedral complex, the six ligands approach along the axes (x, y, z). Consequently, the d-orbitals lying along the axes (dx2-y2 and dz2) experience greater repulsion from the negative charge of the ligands and are raised in energy, while those lying between the axes (dxy, dyz, dzx) are lowered in energy, causing d-orbital splitting.

Detailed Options Breakdown
Option : Covalent bonding between metal and ligands

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

Option 1: The approach of ligands resulting in electrostatic repulsion with d-electrons (Correct Answer)

Correct choice. Refer to the step-by-step verified solution guidelines above for details.

Option 2: Magnetic interactions between unpaired electrons

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

Option 3: Formation of pi-back bonds

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

💡 Study Guide: This question tests core syllabus concepts from Coordination Compounds. For formulas, key summaries, and mock exam reference guides, read the full Coordination Compounds Revision Notes.
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