MCQChemistry

NCERT · Class 12 · Chemistry · Coordination CompoundsWhat is the hybridization and magnetic nature of Ni(CN)42-?

Step-by-Step Solution

In [Ni(CN)4]2-, the oxidation state of Nickel is +2 (Ni2+, configuration 3d8). Cyanide (CN-) is a strong field ligand, which causes pairing of the 3d electrons. This leaves an empty d orbital, resulting in dsp2 hybridization for square planar geometry. Since all electrons are paired, it is diamagnetic.

Detailed Options Breakdown
Option : sp3, paramagnetic

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

Option 1: dsp2, diamagnetic (Correct Answer)

Correct choice. Refer to the step-by-step verified solution guidelines above for details.

Option 2: sp3d2, paramagnetic

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

Option 3: dsp2, paramagnetic

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Coordination Compounds.

💡 Study Guide: This question tests core syllabus concepts from Coordination Compounds. For formulas, key summaries, and mock exam reference guides, read the full Coordination Compounds Revision Notes.
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