MP Board · Class 12 · Chemistry · The d-and f-Block ElementsExplain the general characteristics of transition elements (d-block elements) with respect to the following properties: (i) Electronic configuration, (ii) Metallic character, (iii) Oxidation states, and (iv) Formation of colored ions. Support your explanation with appropriate reasons for each property.
Step-by-Step Solution
Transition elements, also known as d-block elements, occupy the middle portion of the periodic table between s-block and p-block elements. Their unique properties are a result of the progressive filling of d-orbitals. Below is the detailed explanation of their characteristics:
(i) Electronic Configuration
- The general outer electronic configuration of transition elements is represented as $(n-1)d^{1-10}ns^{1-2}$.
- In these elements, the last electron enters the penultimate $(n-1)d$ energy level.
- Exceptions to the Aufbau principle occur due to the extra stability of half-filled and completely filled d-subshells (e.g., Chromium $3d^54s^1$ and Copper $3d^{10}4s^1$).
(ii) Metallic Character
- Almost all transition elements exhibit typical metallic properties such as high tensile strength, ductility, malleability, high thermal and electrical conductivity, and metallic luster.
- These properties are due to the presence of a large number of valence electrons in their outer shells and strong interatomic metallic bonding.
- The involvement of both $(n-1)d$ and $ns$ electrons in metallic bonding leads to very high melting and boiling points and high enthalpies of atomization compared to s-block metals.
(iii) Oxidation States
- Transition metals exhibit variable oxidation states because the energy difference between $(n-1)d$ and $ns$ orbitals is very small.
- Consequently, electrons from both the outermost $s$-orbitals and penultimate $d$-orbitals can participate in chemical bonding.
- They show a minimum oxidation state equal to the number of $ns$ electrons and a maximum oxidation state equal to the sum of $ns$ and $(n-1)d$ electrons (e.g., Manganese shows oxidation states from +2 to +7).
(iv) Formation of Colored Ions
- Most of the transition metal ions and their compounds are colored in both solid and aqueous states.
- This color is attributed to the presence of unpaired d-electrons and $d-d$ electronic transitions.
- When visible light falls on a transition metal ion, the d-electrons absorb specific frequencies of light and get promoted from lower energy d-orbitals to higher energy d-orbitals (known as $d-d$ transition). The remaining transmitted or reflected light gives the characteristic complementary color to the compound.
💡 Study Guide: This question tests core syllabus concepts from The d-and f-Block Elements. For formulas, key summaries, and mock exam reference guides, read the full The d-and f-Block Elements Revision Notes.