MCQChemistry

MP Board · Class 12 · Chemistry · Haloalkanes and HaloarenesWhat is the major product formed when chlorobenzene is treated with $Cl2$ in the presence of anhydrous $FeCl3$?

Step-by-Step Solution

Reaction of chlorobenzene with chlorine in the presence of anhydrous $FeCl_3$ gives a mixture of 1,4-dichlorobenzene and 1,2-dichlorobenzene, where 1,4-dichlorobenzene (p-isomer) is the major product due to lesser steric hindrance.

Detailed Options Breakdown
Option : 1,2-Dichlorobenzene

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Haloalkanes and Haloarenes.

Option 1: 1,4-Dichlorobenzene (Correct Answer)

Correct choice. Refer to the step-by-step verified solution guidelines above for details.

Option 2: Chlorobenzene

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Haloalkanes and Haloarenes.

Option 3: Hexachlorobenzene

Incorrect choice. This distractor represents a common misunderstanding of the core principles of Haloalkanes and Haloarenes.

💡 Study Guide: This question tests core syllabus concepts from Haloalkanes and Haloarenes. For formulas, key summaries, and mock exam reference guides, read the full Haloalkanes and Haloarenes Revision Notes.
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