MP Board · Class 12 · Chemistry · ElectrochemistryWhat is Kohlrausch's law of independent migration of ions?

Kohlrausch's law of independent migration of ions states unequivocally that the limiting molar conductivity of any given electrolyte, evaluated at infinite dilution, can be mathematically expressed as the exact sum of the individual ionic contributions coming from each of its constituent cations and anions. This important principle implies that each individual ion makes a definite, independent contribution to the overall total molar conductivity of the electrolytic solution, regardless of the nature of the associated counter ion present in the medium.