MP Board · Class 10 · Science · Periodic Classification of ElementsDiscuss the Modern Periodic Table in detail. Explain how the Modern Periodic Law overcomes the limitations of Mendeleev's Periodic Table and describe the trends in modern periodic classification (Valency, Atomic Size, Metallic and Non-Metallic character).
Step-by-Step Solution
Introduction to Modern Periodic Law\nIn 1913, Henry Moseley showed that the atomic number of an element is a more fundamental property than its atomic mass. Consequently, the Modern Periodic Law was formulated: 'Properties of elements are a periodic function of their atomic number.' The Modern Periodic Table arranges elements in order of increasing atomic numbers in 18 vertical columns (groups) and 7 horizontal rows (periods).
Resolution of Mendeleev's Limitations
- Position of Isotopes: Since isotopes have the same atomic number, they occupy the exact same position in the modern periodic table, resolving the isotope dilemma.
- Anomalous Pairs: Ordering by atomic number naturally places elements in correct sequence without violating mass order discrepancies (e.g., Cobalt with atomic number 27 comes before Nickel with 28).
- Cause of Periodicity: Periodicity is caused by the repetition of similar valence shell electronic configurations at regular intervals.
Trends in Modern Periodic Table
- Valency: Valency remains the same down a group as the number of valence electrons is constant. Across a period from left to right, valency first increases from 1 to 4 and then decreases to 0.
- Atomic Size (Radius): Atomic radius decreases across a period from left to right due to an increase in effective nuclear charge, which pulls electrons closer. It increases down a group due to the addition of new electronic shells.
- Metallic and Non-Metallic Character: Metallic character decreases across a period (left to right) and increases down a group, as the tendency to lose electrons decreases across a period and increases down a group. Non-metallic character follows the exact opposite trend.
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