MP Board · Class 10 · Science · Carbon and its CompoundsWhat is a homologous series? Write any four characteristics of a homologous series. Write the molecular formula and structural formula of the third and fifth members of the homologous series of alcohols.
Step-by-Step Solution
Definition of Homologous Series\nA homologous series is a family of organic compounds having similar chemical properties, all members of which contain the same functional group and can be represented by a general formula, in which each successive member differs from the previous one by a $-CH_2-$ group (or a molecular mass difference of 14u).
Characteristics of a Homologous Series
- General Formula: All members of a homologous series can be represented by a single general chemical formula. For example, alcohols are represented by $C_n{H}_{2n+1}OH$.
- Difference in Molecular Formula: Any two adjacent (successive) members of the series differ by a $-CH_2-$ group in their molecular formulas.
- Difference in Molecular Mass: The difference in molecular mass between any two successive members is 14 atomic mass units (u) (since carbon has mass 12u and two hydrogens have mass 2u).
- Chemical Properties: All members of a homologous series show similar chemical properties because they contain the same functional group. For example, all alcohols react with sodium to evolve hydrogen gas.
- Gradation in Physical Properties: The physical properties of the members, such as melting point, boiling point, and solubility, show a gradual gradation (increase or decrease) with an increase in molecular mass due to an increase in intermolecular forces.
Members of the Homologous Series of Alcohols\nThe general formula for alcohols is $C_n{H}_{2n+1}OH$.
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Third Member of Alcohol Series ($n = 3$):
- Substituting $n = 3$ in $C_n{H}{2n+1}OH$ gives: $C_3{H}{2(3)+1}OH \Rightarrow C_3H_7OH$ (Propanol)
- Molecular Formula: $C_3H_8O$ (or $C_3H_7OH$)
- Structural Formula: $CH_3 - CH_2 - CH_2 - OH$
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Fifth Member of Alcohol Series ($n = 5$):
- Substituting $n = 5$ in $C_n{H}{2n+1}OH$ gives: $C_5{H}{2(5)+1}OH \Rightarrow C_5H_{11}OH$ (Pentanol)
- Molecular Formula: $C_5H_{12}O$ (or $C_5H_{11}OH$)
- Structural Formula: $CH_3 - CH_2 - CH_2 - CH_2 - CH_2 - OH$
💡 Study Guide: This question tests core syllabus concepts from Carbon and its Compounds. For formulas, key summaries, and mock exam reference guides, read the full Carbon and its Compounds Revision Notes.